Hazardous waste, Class 9 Hazmat shipment. Underwriters Laboratories require trained technician for replacement of these batteries. High cost and safety concerns limit to use in civilian applications. In long storage, forms passivation layer on anode, which may lead to temporary voltage delay when put into service. High-current cells are used in military applications.
Low-current cells are used for portable electronics and memory backup. Has relatively high internal impedance and limited short-circuit current. A negligible amount of gas generated in nominal use, limited amount under abuse. Can operate down to −55 ☌, where it retains over 50% of its rated capacity. Lithium tetrachloroaluminate in thionyl chloride Cathode is often designed as a paste of iron sulfide powder mixed with powdered graphite. 2.5 times higher lifetime for high current discharge regime than alkaline batteries, better storage life due to lower self-discharge(10–20 years). As such, Energizer lithium cells of AA and AAA size employ this chemistry. Called "voltage-compatible" lithium, because it can work as a replacement for alkaline batteries with its 1.5 V nominal voltage. Propylene carbonate, dioxolane, dimethoxyethane Used in aerospace applications, qualified for space since 1976, military applications both terrestrial and marine, in missiles, and in artificial cardiac pacemakers. Used for low to moderate current applications in memory and clock backup batteries. Compared to manganese dioxide (CR), which has the same nominal voltage, it provides more reliability. Lithium tetrafluoroborate in propylene carbonate, dimethoxyethane, or gamma-butyrolactoneĬathode material formed by high-temperature intercalation of fluorine gas into graphite powder. 1,2-Dimethoxyethane is a REACH candidate substance of very high concern. High self-discharge at high temperatures. With discharge, the internal impedance rises and the terminal voltage decreases. Operational temperature ranges from -30 ☌ to 60 ☌. High energy density per both mass and volume. Suitable for low-drain, long-life, low-cost applications.
The most common consumer-grade lithium battery, about 80% of the lithium battery market.
Lithium perchlorate in an organic solvent ( propylene carbonate and dimethoxyethane in many common cells ) It has been suggested that this table be split out into another article. As designed these primary systems use a charged cathode, that being an electro-active material with crystallographic vacancies that are filled gradually during discharge. The battery requires from 0.15 to 0.3 kg of lithium per kWh. The term "lithium battery" refers to a family of different lithium-metal chemistries, comprising many types of cathodes and electrolytes but all with metallic lithium as the anode. Lithium batteries are widely used in portable consumer electronic devices. Pure lithium will instantly react with water, or even moisture in the air the lithium in lithium ion batteries is in a less reactive compound. Lithium is especially useful, because its ions can be arranged to move between the anode and the cathode, using an intercalated lithium compound as the cathode material but without using lithium metal as the anode material. Depending on the design and chemical compounds used, lithium cells can produce voltages from 1.5 V (comparable to a zinc–carbon or alkaline battery) to about 3.7 V.ĭisposable primary lithium batteries must be distinguished from secondary lithium-ion or a lithium-polymer, which are rechargeable batteries. They stand apart from other batteries in their high charge density and high cost per unit.
These types of batteries are also referred to as lithium-metal batteries. Lithium batteries are primary batteries that have metallic lithium as an anode. The top object is a battery of three lithium-manganese dioxide cells, the bottom two are lithium-iron disulfide cells and are compatible with 1.5 volt alkaline cells.